Attach value of column to value of position in list

If you have an enumlist of, for example, employee names and for each of the employees in the list you have a start time and end time for a job in the same row, is it possible to connect the values of the columns to the position of the employee in the list? For example:

Here I have a list of employees.

And here I have some columns for start time/end time/work completed for each of the employees in that list.

Is it possible to, for example, connect the first 3 columns to the first person in the list and the second 3 columns to the second person in the list. This would be for purposes of pulling hours data at the end of the week for each employee though some work orders will have more than 1 employee assigned.